時空間で精密制御した輻射場による表面反応プロセス

研究課題

体系的番号	JPMJCR20R4
DOI	https://doi.org/10.52926/JPMJCR20R4
研究代表者	吉信淳東京大学, 物性研究所, 教授
研究期間 (年度)	2020 – 2025
概要	本研究では、THzパルスによる吸着種の低エネルギー振動モードの選択励起とポラリトン形成によるポテンシャル変調を駆使して，時空間領域で精密制御した輻射場により表面反応プロセスを能動的に駆動します．全ての振動モードに統計的にエネルギーが分配される熱反応の欠点を回避し，反応の活性化障壁を下げ、反応を直接駆動するモードを選択励起することで、より低い温度・少ないエネルギーでの反応駆動を目指します。
研究領域	新たな生産プロセス構築のための電子やイオン等の能動的制御による革新的反応技術の創出

主な研究成果
(26件)

すべて 2024

すべて雑誌論文 (26件) (国際共著 4件、査読あり 25件、オープンアクセス 12件)

[雑誌論文] Sequential C-F Bond Transformation of the Difluoromethylene Unit in Perfluoroalkyl Groups: A Combination of Fine-Tuned Phenothiazine Photoredox Catalyst and Lewis Acid2024
- 著者名
  Sugihara, Naoki, Nishimoto, Yoshihiro, Osakada, Yasuko, Fujitsuka, Mamoru, Abe, Manabu, Yasuda, Makoto
- 雑誌名
  
  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  
  巻: 63 号: 14
- 査読あり / オープンアクセス
[雑誌論文] Crucial Roles of Leaving Group and Open-Shell Cation in Photoreaction of (Coumarin-4-yl)methyl Derivatives2024
- 著者名
  Nguyen, Hai Dang, Abe, Manabu
- 雑誌名
  
  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  
  巻: 146 号: 15 ページ: 10993-11001
- 査読あり / オープンアクセス
[雑誌論文] Introduction: Persistent and Stable Organic Radicals2024
- 著者名
  Takashi Kubo, Manabu Abe
- 雑誌名
  
  Chemical Reviews
  
  巻: 124 号: 8 ページ: 4541-4542
- オープンアクセス
[雑誌論文] Optochemical control of slow-wave sleep in the nucleus accumbens of male mice by a photoactivatable allosteric modulator of adenosine A2A receptors2024
- 著者名
  Roy, Koustav, Zhou, Xuzhao, Otani, Rintaro, Yuan, Ping-Chuan, Ioka, Shuji, Vogt, Kaspar E., Kondo, Tamae, Farag, Nouran H. T., Ijiri, Haruto, Wu, Zhaofa, Chitose, Youhei, Amezawa, Mao, Uygun, David S., Cherasse, Yoan, Nagase, Hiroshi, Li, Yulong, Yanagisawa, Masashi, Abe, Manabu, Basheer, Radhika, Wang, Yi-Qun, Saitoh, Tsuyoshi, Lazarus, Michael
- 雑誌名
  
  NATURE COMMUNICATIONS
  
  巻: 15 号: 1
- 査読あり / オープンアクセス / 国際共著
[雑誌論文] α-Cleavage of 2,2-Diazido-2,3-dihydroinden-1-one in Solution and Cryogenic Matrices2024
- 著者名
  James, Brandi, Sriyarathne, H. Dushanee M., Banerjee, Upasana, Henarath Mohottige, Wandana K. S., Crabtree, Ben, Leon, Aliz, Hong, Miao, Tariq, Javeria, Alhayani, Taha, Abe, Manabu, Ault, Bruce S., Gudmundsdottir, Anna D
- 雑誌名
  
  JOURNAL OF ORGANIC CHEMISTRY
  
  巻: 89 号: 10 ページ: 7125-7137
- 査読あり / 国際共著
[雑誌論文] Element-specific cluster growth on the two-dimensional metal?organic network2024
- 著者名
  Noriyuki Tsukahara, Ryuichi Arafune, Jun Yoshinobu
- 雑誌名
  
  Japanese Journal of Applied Physics
- 査読あり
[雑誌論文] Tunneling electron induced luminescence from In films on Si(111)2024
- 著者名
  K. Kuroishi, H. Okuyama, S. Hatta, and T. Aruga
- 雑誌名
  
  Phys. Rev. B
  
  巻: 109 ページ: 235410
- 査読あり
[雑誌論文] Ultra-Broadband Detection of Coherent Infrared Pulses by Sum-Frequency Generation Spectroscopy in Reflection Geometry2024
- 著者名
  Risako Kameyama, Shunsuke Tanaka, Yuta Murotani, Takuya Matsuda, Natsuki Kanda, Ryusuke Matsunaga, Jun Yoshinobu
- 雑誌名
  
  Optics Letters
- 査読あり
[雑誌論文] CO2 Capture and Electrochemical Reduction of Low-Concentration CO2 Using a Re(I)-Complex Catalyst in Ethanol2024
- 著者名
  Miyaji, Masahiko, Tamaki, Yusuke, Kamogawa, Kei, Abiru, Yuto, Abe, Manabu, Ishitani, Osamu
- 雑誌名
  
  ACS CATALYSIS
  
  巻: 14 号: 13 ページ: 10403-10411
- 査読あり
[雑誌論文] Sulfur atom effect on the photochemical release of benzylamine from caged amines2024
- 著者名
  Nguyen, Hai Dang, Abe, Manabu
- 雑誌名
  
  CHEMISTRY LETTERS
  
  巻: 53 号: 6
- 査読あり / オープンアクセス
[雑誌論文] Study on factors affecting quantum yield for the design of improved ortho-nitrobenzyl photoremovable protecting groups2024
- 著者名
  Nguyen, Linh Tran Bao, Abe, Manabu
- 雑誌名
  
  BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
  
  巻: 97 号: 6
- 査読あり / オープンアクセス
[雑誌論文] Temporal-Focusing Multiphoton Excitation Single-Molecule Localization Microscopy Using Spontaneously Blinking Fluorophores2024
- 著者名
  Lai, Jian-Zong, Lin, Chun-Yu, Chen, Shean-Jen, Cheng, Yu-Min, Abe, Manabu, Lin, Tzu-Chau, Chien, Fan-Ching
- 雑誌名
  
  ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  
  巻: 63 号: 27
- 査読あり / オープンアクセス / 国際共著
[雑誌論文] Molecular engineering of coumarins for enhanced 2-photon absorption property2024
- 著者名
  Zhang, Fan, Wang, Yong-Hsin, Wu, Cheng-Lin, Lin, Tzu-Chau, Abe, Manabu
- 雑誌名
  
  CHEMISTRY LETTERS
  
  巻: 53 号: 7
- 査読あり / オープンアクセス / 国際共著
[雑誌論文] Programmable generation of counterrotating bicircular light pulses in the multi-terahertz frequency range2024
- 著者名
  Kotaro Ogawa, Natsuki Kanda, Yuta Murotani, and Ryusuke Matsunaga
- 雑誌名
  
  Nature Communications
  
  巻: 15 ページ: 6310
- 査読あり / オープンアクセス
[雑誌論文] Organophotocatalytic access to C-glycosides: multicomponent coupling reactions using glycosyl bromides.2024
- 著者名
  Naoya Sawada, Ziyi Yu, Hiryu Takinami, Daichi Inoue, Titli Ghosh, Norihiko Sasaki, Toshiki Nokami, Tsuyoshi Taniguchi, Manabu Abe, Takashi Koike
- 雑誌名
  
  Chemical communications (Cambridge, England)
  
  巻: 60 号: 66 ページ: 8684-8687
- 査読あり
[雑誌論文] Water orientation on platinum surfaces controlled by step sites2024
- 著者名
  Naoki Nagatsuka, Takumi Otsuki, Shota Kamibashira, Takanori Koitaya and Kazuya Watanabe
- 雑誌名
  
  J. Chem. Phys.
  
  巻: 161
- 査読あり
[雑誌論文] Design and synthesis of a 2,5-Diarylthiophene chromophore for enhanced near-infrared two-photon uncaging efficiency of calcium ions2024
- 著者名
  Tran, Tam Thi Thanh, Abe, Manabu
- 雑誌名
  
  PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES
  
  巻: 23 号: 10 ページ: 1811-1827
- 査読あり
[雑誌論文] Elucidation of CO Oxidation and CO2 Desorption Dynamics on Pt(111) by van der Waals DFT Calculations: Hyperthermal Kinetic Energy, Sharp Desorption Angle, and Excited Vibrational States2024
- 著者名
  Hongyu Li, Yuta Kataoka, Shunsuke Tanaka, Jun Haruyama, Osamu Sugino, Jun Yoshinobu
- 雑誌名
  
  The Journal of Physical Chemistry C
- 査読あり
[雑誌論文] Twin-free growth of ultrathin Bi2Se3 films on CaF2(111)/Si(111)2024
- 著者名
  S. Hatta, S. Higaki, H. Okuyama, and T. Aruga
- 雑誌名
  
  Cryst. Growth Des.
  
  巻: 24 号: 23 ページ: 10038-10045
- 査読あり
[雑誌論文] Chemical process of hydrogen and formic acid on a Pd-deposited Cu(111) surface studied by high-resolution X-ray photoelectron spectroscopy and density functional theory calculations2024
- 著者名
  Wataru Osada, Masahiro Hasegawa, Yuichiro Shiozawa, Kozo Mukai, Shinya Yoshimoto, Shunsuke Tanaka, Mitsuaki Kawamura, Taisuke Ozaki, Jun Yoshinobu
- 雑誌名
  
  Physical Chemistry Chemical Physics
- 査読あり
[雑誌論文] Surface Orientation Dependent Dissociation of Formic Acid and Adsorption States of Formate on Copper2024
- 著者名
  Hiroki Yasumura, Atsuki Mizutani, Naoki Nagatsuka, Kazuya Watanabe and Takanori Koitaya
- 雑誌名
  
  J. Phys. Chem. C
  
  巻: 129 号: 2 ページ: 1216-1227
- 査読あり
[雑誌論文] Emergence of high-mobility carriers in topological kagome bad metal2024
- 著者名
  Takuya Matsuda, Tomoya Higo, Kenta Kuroda, Takashi Koretsune, Natsuki Kanda, Yoshua Hirai, Hanyi Peng, Takumi Matsuo, Cedric Bareille, Andrei Varykhalov, Naotaka Yoshikawa, Jun Yoshinobu, Takeshi Kondo, Ryo Shimano, Satoru Nakatsuji, Ryusuke Matsunaga
- 雑誌名
  
  Physical Review Materials
  
  巻: 9 号: 1
- 査読あり
[雑誌論文] Far-ultraviolet plexciton formation in water-covered indium clusters2024
- 著者名
  N. Nagatsuka, R. Matsuguchi, K. Watanabe, T. Koitaya, D. Yamamoto, H. Okuyama and T. Yasuike
- 雑誌名
  
  J. Phys. Chem. Lett.
  
  巻: 16 号: 5 ページ: 1276-1281
- 査読あり
[雑誌論文] Design, Synthesis, and Biological Evaluation of BODIPY-Caged Resiquimod as a Dual-Acting Phototherapeutic2024
- 著者名
  Eslam Roshdy, Haruto Taniguchi, Yoki Nakamura, Haruko Takahashi, Yutaka Kikuchi, Ismail Celik, Elsayed S. I. Mohammed, Yasuhiro Ishihara, Norimitsu Morioka, Manabu Abe
- 雑誌名
  
  Journal of Medicinal Chemistry
- 査読あり / オープンアクセス
[雑誌論文] Valley polarization dynamics of photoinjected carriers at the band edge in room-temperature silicon studied by terahertz polarimetry2024
- 著者名
  Ami M. Shirai, Yuta Murotani, Tomohiro Fujimoto, Natsuki Kanda, Jun Yoshinobu, Ryusuke Matsunaga
- 雑誌名
  
  Physical Review B
- 査読あり / オープンアクセス
[雑誌論文] Direct Observation of Dioxymethylene and Formaldehyde as Hydrogenation Products of Formate Species on the Hydrogen‐Adsorbed Cu(997) Surface2024
- 著者名
  Haruka Yoshioka, Wataru Osada, Kozo Mukai, Shunsuke Tanaka, Jun Yoshinobu
- 雑誌名
  
  ChemCatChem
- 査読あり / オープンアクセス

時空間で精密制御した輻射場による表面反応プロセス

研究代表者

吉信 淳 東京大学, 物性研究所, 教授

主な研究成果

[雑誌論文] Sequential C-F Bond Transformation of the Difluoromethylene Unit in Perfluoroalkyl Groups: A Combination of Fine-Tuned Phenothiazine Photoredox Catalyst and Lewis Acid2024

著者名

雑誌名

[雑誌論文] Crucial Roles of Leaving Group and Open-Shell Cation in Photoreaction of (Coumarin-4-yl)methyl Derivatives2024

著者名

雑誌名

[雑誌論文] Introduction: Persistent and Stable Organic Radicals2024

著者名

雑誌名

[雑誌論文] Optochemical control of slow-wave sleep in the nucleus accumbens of male mice by a photoactivatable allosteric modulator of adenosine A2A receptors2024

著者名

雑誌名

[雑誌論文] α-Cleavage of 2,2-Diazido-2,3-dihydroinden-1-one in Solution and Cryogenic Matrices2024

著者名

雑誌名

[雑誌論文] Element-specific cluster growth on the two-dimensional metal?organic network2024

著者名

雑誌名

[雑誌論文] Tunneling electron induced luminescence from In films on Si(111)2024

著者名

雑誌名

[雑誌論文] Ultra-Broadband Detection of Coherent Infrared Pulses by Sum-Frequency Generation Spectroscopy in Reflection Geometry2024

著者名

雑誌名

[雑誌論文] CO2 Capture and Electrochemical Reduction of Low-Concentration CO2 Using a Re(I)-Complex Catalyst in Ethanol2024

著者名

雑誌名

[雑誌論文] Sulfur atom effect on the photochemical release of benzylamine from caged amines2024

著者名

雑誌名

[雑誌論文] Study on factors affecting quantum yield for the design of improved ortho-nitrobenzyl photoremovable protecting groups2024

著者名

雑誌名

[雑誌論文] Temporal-Focusing Multiphoton Excitation Single-Molecule Localization Microscopy Using Spontaneously Blinking Fluorophores2024

著者名

雑誌名

[雑誌論文] Molecular engineering of coumarins for enhanced 2-photon absorption property2024

著者名

雑誌名

[雑誌論文] Programmable generation of counterrotating bicircular light pulses in the multi-terahertz frequency range2024

著者名

雑誌名

[雑誌論文] Organophotocatalytic access to C-glycosides: multicomponent coupling reactions using glycosyl bromides.2024

著者名

雑誌名

[雑誌論文] Water orientation on platinum surfaces controlled by step sites2024

著者名

雑誌名

[雑誌論文] Design and synthesis of a 2,5-Diarylthiophene chromophore for enhanced near-infrared two-photon uncaging efficiency of calcium ions2024

著者名

雑誌名

[雑誌論文] Elucidation of CO Oxidation and CO2 Desorption Dynamics on Pt(111) by van der Waals DFT Calculations: Hyperthermal Kinetic Energy, Sharp Desorption Angle, and Excited Vibrational States2024

著者名

雑誌名

[雑誌論文] Twin-free growth of ultrathin Bi2Se3 films on CaF2(111)/Si(111)2024

著者名

雑誌名

[雑誌論文] Chemical process of hydrogen and formic acid on a Pd-deposited Cu(111) surface studied by high-resolution X-ray photoelectron spectroscopy and density functional theory calculations2024

著者名

雑誌名

[雑誌論文] Surface Orientation Dependent Dissociation of Formic Acid and Adsorption States of Formate on Copper2024

著者名

雑誌名

[雑誌論文] Emergence of high-mobility carriers in topological kagome bad metal2024

著者名

雑誌名

[雑誌論文] Far-ultraviolet plexciton formation in water-covered indium clusters2024

著者名

雑誌名

[雑誌論文] Design, Synthesis, and Biological Evaluation of BODIPY-Caged Resiquimod as a Dual-Acting Phototherapeutic2024

著者名

雑誌名

[雑誌論文] Valley polarization dynamics of photoinjected carriers at the band edge in room-temperature silicon studied by terahertz polarimetry2024

著者名

雑誌名

[雑誌論文] Direct Observation of Dioxymethylene and Formaldehyde as Hydrogenation Products of Formate Species on the Hydrogen‐Adsorbed Cu(997) Surface2024

吉信淳東京大学, 物性研究所, 教授